Pamp,
My charcoal canister is left in place but plugged on the vacumn side. ( I don't have any emissions eq. ) While the battery tray is welded, below the battery are two bolts that hold the cannister by a strap.
With a motronic... some hook it up, some don't. There's a provision for a purge valve though. But If you have vacumn hooked up full time then , no: disconnect it. That's not how it works.
At some point ( late 72,,,) carbed cars also had a return line. Don't know why or what for.( stupid emissions)
Since you haven't collapsed your tank yet, you're probably golden on the gas cap vent. It's hidden behind the gasket or seal anyway. I know mine is vented ; it's one way though, only into the tank.
Gas smells can come from a lot of places... loose hoses/ clamps, sender ring gasket, cracked rubber at the filler, loose neck, bad overflow hose. I once saw a car with 4 gas filters on it.. guess the owner thought more was better untill he didn't get gas because of the restrictions.
if I didn't answer everthing- try again. Always glad to help.