It's a brass tank so it's likely brazed or silver soldered and the melting point of those alloys are far higher than powder coating temperatures. They are in the high 800's degrees or so. If it was my tank I wouldn't hesitate doing it.
Thanks for the solder confirmation Luis. I noticed on the web site that put together RB1971's Inka Hot Rod that they have a powder coated expansion tank in their photo section that looks very nice.
I don't think that is accurate - I believe that expansion tanks (and radiators) are held together with lead-tin solder. So paint, rather than powder coating, is the better choice of finish.
I learned the hard way not to do this. I found a used tank that needed paint and figured I'd send it in with some other parts I was powder coating. While being baked the bracket came off the bottom, it fell on the ground causing a big dent and a fair amount of solder was rattling around inside. It's now abstract art on my garage floor
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